This technique is demonstrated by forming a superhydrophobic surface in the first step, and then laser patterning to allow bottom surface exposed. Those exposed surface was then metallized by a process involving “silane compound modification + nano-Palladium catalyst activation”. In particular, TiO2 nanoparticles is coated by spin-coating on the glass substrate. Then, the surface with TiO2 nanoparticles is modified by Perfluorooctyltriethoxysilane (PFOTES) in order to form a superhydrophobic surface. The water contact angle of the surface exceeds 150 degree at this stage. The superhydrophobic layer acts like a shelter that could prevent electroless plating reaction from the substrate surface. After that, laser beam is applied on the superhydrophobic surface to remove PFOTES/TiO2 so that the specific pattern is exposed. Finally, selective metallization is accomplished on the exposed surface using home-made Pd nanoparticles and commercial electroless metal solution.