Among promising approaches, overcoming the limitations of other techniques, luminescent methods are of great interest. While the idea is not new [1], a real breakthrough using this technique was not yet achieved. Combining a high sensitivity and accuracy as well as broad range of temperature usability within one temperature sensor appeared challenging [2,3].
In this presentation we shall prove that Pr3+ luminescence characteristics may offer a lot in this field. While in some compositions this ion generates only 4f®4f luminescence due to relaxation of the higher 3P0 and lower 1D2 levels, in some others also 5d®4f luminescence may take place. We explored the possibility to use all these three luminescent components to sense the temperature accurately and in a broad range. The main argument for that is that all the three emissions are characterized by different mechanisms of their thermal quenching. Furthermore, temperature strongly affects the non-radiative relaxation between the three levels. Our presentation will show first results of the approach presented above using data for Sr2GeO4:Pr and will prove a validity and potential of this new attitude. Figure 1 presents profound changes in emission spectra of Sr2GeO4:Pr in the range of 17-600 K.
[1] P. Neubert, US2085508 A, 1937.
[2] L. D. Carlos, F. Palacio, Thermometry at the Nanoscale: Techniques and Selected Applications, Royal Society of Chemistry, Oxfordshire 2016.
[3] C. D. S. Brites, P. P. Lima, N. J. O. Silva, A. Millán, V. S. Amaral, F. Palacio, L. D. Carlos, Nanoscale 2012, 4, 4799.