In this study, 2D nanostructured materials and their hybrids were investigated for wearable gas sensing applications. Graphene oxide (GO) was incorporated with TiO2 nanoparticles, and the composite was photo-reduced under UV irradiation. Room temperature gas sensing was carried out against various VOC gases, and sensing performance was evaluated by comparing with pure GO. With the tailored hetero-junction at the interfaces of GO and TiO2, the composite can identify ethanol, methanol, and acetone, and its gas response was enhanced. After photo-reduction, the gas sensing behavior was converted from n-type to p-type due to reduction of GO. Color change of the composites was also observed. In addition, we introduced new 2D nanostructured materials, MXenes, for gas sensing. Ti3C2 (MXene) was synthesized by selectively eliminating Al from Ti3AlC2 (MAX) using LiF salt and HCl acid. Ti3C2 was deposited as sensing material on a flexible polymer film using facile drop casting. The structural and morphological study of the prepared Ti3C2 was conducted by XRD, SEM, and EDS, and the surface bonding was probed by FTIR. The sensing properties of the Ti3C2 sensor were investigated with various reducing gases at RT, and the predicted sensing mechanism was proposed. [5]
References
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[2] Choi, S. J., & Kim, I. D. (2018). Recent Developments in 2D Nanomaterials for Chemiresistive-Type Gas Sensors. Electronic Materials Letters, 1-40.
[3] Meng, F. L., Guo, Z., & Huang, X. J. (2015). Graphene-based hybrids for chemiresistive gas sensors. TrAC Trends in Analytical Chemistry, 68, 37-47.
[4] Yu, X. F., Li, Y. C., Cheng, J. B., Liu, Z. B., Li, Q. Z., Li, W. Z., ... & Xiao, B. (2015). Monolayer Ti2CO2: a promising candidate for NH3 sensor or capturer with high sensitivity and selectivity. ACS applied materials & interfaces, 7(24), 13707-13713.
[5] Lee, E., VahidMohammadi, A., Prorok, B. C., Yoon, Y. S., Beidaghi, M., & Kim, D. J. (2017). Room Temperature Gas Sensing of Two-Dimensional Titanium Carbide (MXene). ACS applied materials & interfaces, 9(42), 37184-37190.
This research was partially supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP), grant funded by the Korea Government Ministry of Trade, Industry and Energy (20158520000210), and Agency for Defense Development (ADD) as global cooperative research for high performance and light weight bio-urine based fuel cell (UD160050BD).