In this presentation, we will introduce our recent progress in developing aqueous organic flow battery materials and systems. Among a variety of organic candidates being investigated, a few have demonstrated high effective electron solubilities >3 M, favorable redox potentials to enable high cell voltages, and highly scalable synthesis leading to cost-effectiveness. More importantly, we have achieved basic structure-property understandings of the key factors that govern the solubility and chemical stability of organic redox-active materials. These have provided guidance for rational materials design and development strategies to harvest significantly improved energy density and cyclability of flow batteries.
References
- X. Wei, W. Pan, W. Duan, A. Hollas, Z. Yang, B. Li, Z. Nie, J. Liu,D. Reed, W. Wang, V. Sprenkle, Materials and Systems for Organic Redox Flow Batteries: Status and Challenges. ACS Energy Lett. 2017, 2, 2187.
- A. Hollas, X. Wei, M. Vijayakumar, Z. Nie, B. Li, D. Reed, J. Liu, V. Sprenkle, W. Wang, A Nature-Inspired, Energy-Dense Phenazine-based Anolyte for Aqueous Organic Redox Flow Batteries. Nat. Energy, accepted.
Figure 1. Cycling efficiency and capacity for an aqueous organic flow battery.