Spinel Li₄Ti₅O₁₂ has become an alternative anode material for graphite in lithium ion batteries for large scale electrical energy storage in terms of solving safety issues and improving battery life-time. In order to form a much more bonding between the LTO and current collector, which is beneficial for stable cycling and high rate performance, we introduce a wrinkled graphene between the electrode layer and aluminum current collector to improve the rate performance and cycling performance of Li₄Ti₅O₁₂ electrode. The introduced wrinkled graphene layer provides larger contact area, lower contact resistance, stronger adhesion and better electrode stability of Li₄Ti₅O₁₂ electrode. This excellent electrochemical performance and very simple preparation method makes LTO@G-Al electrodes suitable for high-rate lithium ion batteries.