Thursday, 23 June 2016
Riverside Center (Hyatt Regency)
The higher specific capacity and richness in natural resources makes SiOx-based become a research focus by international scholar in recent years. A lot volume changes of material in the process of cycling which affects the batteries’ cycling performance, thereby limiting its development and usage. While choosing suitable binder is critical to effectively enhance the performance of the silicon oxide (SiOx) that has high specific capacity and easy pulverization. Researched the lithium insertion/extraction properties of SiOx composite electrode which prepared with polyvinylidene fluoride (PVDF), LA132 (which major copolymerization chain is polyacrylonitrile-polyacrylic acid (PAN-PAA)), polyacrylic acid (PAA). Electrochemical cycling tests with a current density of 160mA/g shows that SiOx electrode with conventional binder PVDF results in rapid capacity loss, while aqueous binder LA132 and PAA could dramatically improve cycle performance of SiOx. SiOx with PAA electrode exhibits reversible capacity still up to 1090mAh/g after 50 cycles. The analysis and characterization methods of SEM, EIS, XRD and differential capacity plots, it is prove that amorphous or little crystalline binder have physical or chemical reaction with –OH of SiOx and formed class network constitute. The expansion pulverization of SiOx power limited in original domain and maintained electronic and ionic conductivity effectively, improved cycle performance of materials.
Acknowledgements
The project was supported by the Shanghai Science and Technology Development Fund (15DZ2282000).
References
[1] J. Li, L. Christensen, M. N. Obrovac, K. C. Hewitt and J. R. Dahn. J. Electrochem. Soc., 155(2008): A234-A238.
[2] N. S. Hochgatterer, M. R. Schweiger, S. Koller, P. R. Raimann, T. Wöhrle, C.Wurm and M. Winter. Electrochem. Solid-State Lett. 11(2008): A76-A80.
[3] X. J. Feng, J. Yang, X. L. Yu, Wang J L, Y. N. Nuli. J. Solid State Electrochem, 17(2013):2461-2469.
[4] I. Kovalenko, B. Zdyrko, A. Magasinski, B. Hertzberg, Z. Milicev, R. Burtovyy, I. Luzinov, G. Yushin. Scicence, 334(2011):76-79.