We have been targeting polycarbonates – specifically, poly(trimethylene carbonate) (PTMC) – for Li- and Li-ion batteries. PTMC has a somewhat higher Tg than PEO, but is amorphous and display better mechanical integrity, not least at higher temperatures. The Li+ transference numbers are also much higher than for PEO. We have recently shown that functional Li-batteries can be constructed using PTMC as an electrolyte host for LiTFSI salt [1]. We have also shown that the ion transport and/or mechanical properties can be improved by lowering the Tg through monomer functionalization, cross-linking [2] or through co-polymerization with polyesters [3,4], rendering Li-batteries with room temperature functionality. Moreover, we have been able to significantly improve the device performance by tailoring the battery fabrication procedure using oligomer components [5] and utilized X-ray Photoelectron Spectroscopy to better understand the interfacial chemistry between the SPE and common Li-battery electrode materials [6].
References
[1] Sun, B., Mindemark, J., Edström, K., Brandell, D. Polycarbonate-based solid polymer electrolytes for Li-ion batteries. Solid State Ionics, 262 (2014) 738.
[2] Mindemark, J., Imholt, L., Brandell, D. Synthesis of high molecular flexibility polycarbonates for solid polymer electrolytes. Electrochim. Acta, 175 (2015) 247.
[3] Mindemark, J., Törmä, E., Sun, B., Brandell, D. Copolymers of trimethylene carbonate and ε-caprolactone as electrolytes for lithium-ion batteries. Polymer, 63 (2015) 91.
[4] Mindemark, J., Sun, B., Törmä, E., Brandell, D. High-performance solid polymer electrolytes for lithium batteries operational at ambient temperature. J. Power Sources, 298 (2015) 166.
[5] Sun, B., Mindemark, J., Edström, K., Brandell, D. Realization of High Performance Polycarbonate-based Li-Polymer Batteries. Electrochem. Commun., 52 (2015) 71.