Topic 4: Electrolytes I

261

Fabrication of LiCoO₂/Li₂s-P₂S₅ Composite Cathode By Electrostatic Slurry Spray Deposition for All-Solid-State Lithium Ion Batteries

C. H. Park, S. H. Son, L. Y. Choi, S. W. Lee, and D. Shin (Hanyang University)

262

Investigation of Structural Changes in Bulk-Type All-Solid-State Batteries Using LiCoO₂ Particles with Sulfide Electrolyte Coatings

Y. Ito, M. Otoyama (Osaka Prefecture University), T. Ohtomo (Toyota Motor Corporation), A. Hayashi (Osaka Prefecture University), and M. Tatsumisago (Graduate School of Engineering)

263

The Impact of Different Substituents in Fluorinated Cyclic Carbonates in the Performance of High Voltage Lithium-Ion Battery Electrolyte

C. C. Su, M. He, C. Peebles, and Z. Zhang (Argonne National Laboratory)

264

UV-Curable Solid Polymer Electrolytes Based on Poly(ethylene glycol) and Cardanol Moiety for All-Solid-State Lithium Secondary Batteries (Cancelled)

265

Ionic Liquid Electrolytes for Safer Lithium Batteries: I. Investigation Around Optimal Formulation

M. Moreno Jr. (ENEA, DTE-PCU-SPCT), E. Simonetti Sr. (ENEA, SSPT-PROMAS-MATPRO), G. B. Appetecchi Sr. (ENEA, SSPT-PROMAS-MATPRO, Italy), M. Carewska Sr. (ENEA, DTE-PCU-SPCT), M. Montanino Jr. (ENEA, SSPT-PROMAS-NANO), G. T. Kim Sr. (Karlsruhe Institute of Technology, Helmholtz Institute Ulm), N. Loeffler Jr. (Helmholtz Institute of Ulm, Karlsruhe Institute of Technology), and S. Passerini Sr. (Karlsruhe Institute of Technology (KIT), Helmholtz Institute Ulm (HIU-KIT))

266

Interactions Between Positive and Negative Electrodes in Li-Ion Cells Operated at High Temperature and High Voltage

D. Xiong (Dept. of Chemistry, Dalhousie University), R. Petibon, M. Nie (Dep. of Chemistry, Dalhousie University), L. Ma (Dept. of Chemistry, Dalhousie University), J. Xia (Dep. of Physics, Dalhousie University), and J. R. Dahn (Dalhousie University)

267

Field Assisted Sintering of Li_7-3xLa₃Zr₂Al_xO₁₂ Solid Electrolyte and the Influence of the Microstructure on the Electrochemical Performance

M. Botros (Joint Research Laboratory Nanomaterials, Germany), R. Djenadic, and H. Hahn (Joint Research Laboratory Nanomaterials, Germany, Helmholtz Institute Ulm, Germany)

268

Propylene Carbonate-Based Highly Concentrated Electrolyte Solutions for LiNi_0.5Mn_1.5O₄ Positive Electrodes of Lithium Ion Batteries

T. Doi, R. Masuhara, Y. Shimizu, M. Hashinokuchi, and M. Inaba (Doshisha University)

269

Electrospun Membranes Based on PVDF-PEO Blends for Lithium Batteries

A. La Monaca, C. Arbizzani, F. De Giorgio, M. L. Focarete (Alma Mater Studiorum University of Bologna), D. Fabiani, and M. Zaccaria (Electr. Electron.& Inf. Eng. Dept University of Bologna)

270

In Situ Characterization of Gassing Processes in Lithium-Ion Batteries By Dems-Deirs

B. B. Berkes (Karlsruhe Institute of Technology, INT-BELLA), H. Sommer (Karlsruhe Institute of Technology, INT-BELLA, BASF SE), T. Brezesinski (Karlsruhe Institute of Technology, INT-BELLA), and J. Janek (Karlsruhe Institute of Technology, INT-BELLA, Justus-Liebig-Universität Giessen)

271

DFT-MD Study of Sacrificial Anion Reduction and Li-Ion Diffusion Mechanisms in Superconcentrated Electrolytes

K. Sodeyama (JST-PRESTO, National Institute for Materials Science (NIMS)), Y. Yamada (The University of Tokyo), A. Yamada (Department of Chem. System Eng., The University of Tokyo), and Y. Tateyama (National Institute for Materials Science (NIMS))

272

Solid State Electrolytes Based on Doped Li₇La₃Zr₂O₁₂ Garnets: Crystal Chemistry, Ion Transport and Implementation into Li Batteries (Cancelled)

273

Sulfide Electrolytes: Study of Local Li-Ion Dynamics in Li₃PS₄ Using Li(7) NMR Relaxometry

D. Prutsch, H. Brandstätter, V. Pregartner, D. Wohlmuth, V. Epp (CD-Laboratory for Li Ion Batteries, ICTM, TU-Graz), and M. Wilkening (CD-Lab for Lithium Batteries, Graz Univ. of Technology)

274

Ceramic Polymer Hybrid Electrolyte Based on Li₇La₃Zr₂O₁₂ for Solid-State Batteries (Cancelled)

275

Characterization of Li₂s-P₂S₅ Solid Electrolytes/Alloy Negative Electrodes Interface Using Microelectrode Techniques

M. Chiku, N. Koretaka, E. Higuchi, and H. Inoue (Osaka Prefecture University)

276

Functional Solid-State Polymer Electrolytes through Utilization of Polycarbonates

D. Brandell, B. Sun, and J. Mindemark (Department of Chemistry, Uppsala University)

277

Development of Sulfolane-Based Electrolytes for Li-ionbatteries

T. Zhang (Helmholtz Institute Muenster/FZ-Juelich (IEK-12), University of Muenster/Institute of Physical Chemistry), W. Porcher (CEA Grenoble/LITEN), and E. Paillard (Helmholtz Institute Muenster/FZ-Juelich (IEK-12))

278

Analysis of Surface Deposit Formed on the Binder-Free Si Nanoparticle Electrode in Room-Temperature Ionic Liquid Containing Lithium Bis(trifluoromethanesulfonyl)Amide

K. Ui, K. Kikuchi, R. Saito, Y. Kadoma (Graduate School of Engineering, Iwate University), T. Takeguchi (Faculty of Science and Engineering, Iwate University), S. Kawamura, T. Kakigi, and T. Sukigara (Honda R&D automobile center)

279

Effect of Sintering Temperature on Interfacial Structure and Interfacial Resistance for All-Solid-State Batteries

T. Kato (Graduate School of Engineering, Nagoya University, JST-ALCA), R. Yoshida (Japan Fine Ceramics Center), K. Yamamoto (JFCC), T. Hirayama (Japan Fine Ceramics Center), M. Motoyama (JST-ALCA, Graduate School of Engineering, Nagoya University), W. C. West (California Institute of Technology), and Y. Iriyama (Graduate School of Engineering, Nagoya University, JST-ALCA)

280

Surface Analysis of Li-Ion Electrode-Electrolyte Interfaces: Insights By a Surface Science Approach

R. Hausbrand, M. Fingerle (Darmstadt University of Technology), W. Jaegermann (Technische Universität Darmstadt), N. Schulz, and T. Späth (Darmstadt University of Technology)

281

Mechanistic Illustration of Mononitriles Decomposition in Lithium Ambience Encompassing Development of a Dinitrile-Mononitrile Based Electrolyte System for Lithium Batteries

R. Rohan (NSYS University Taiwan), C. C. Li (NTUT Taiwan), and J. T. Lee (National Sun Yat-sen University)

282

Electrospun Gel Electrolytes for Li-Ion Batteries (Cancelled)

283

Iron and Titanium Substituted LiCoTi_xMn_1-XO₄/LiCo₁-_yFe_yMnO₄: High-Voltage Spinels As Cathode Materials for Li-Ion Batteries

C. Dräger (IAM-ESS - Karlsruhe Institute of Technology), S. Indris, and H. Ehrenberg (IAM-ESS, Karlsruhe Institute of Technology)

284

All-Solid State Rechargeable Batteries: Manufacturing of Composite Cathodes (Cancelled)

285

Photoinitiated Polymerization of Methacrylate/Ionic Liquid Based Polymer Electrolytes: Effect of the Curing Sequence on the Electrochemical Properties

M. Cesbron (Univ. Grenoble Alpes, F-38000 Grenoble France), S. Oukassi, A. Bazin, G. Piana, V. Armel, H. Porthault, S. Poncet, F. Geffraye, and R. Salot (CEA, LETI, MINATEC Campus, 38054 Grenoble, France)

286

Electrochemical Investigation of Thermodynamic and Transport Phenomena in LP30 Electrolyte with Various Concentrations of Conducting Salt

K. Fröhlich, G. Bimashofer (AIT Austrian Institute of Technology GmbH), G. Fafilek (Vienna University of Technology), F. Pichler, M. Cifrain (Kompetenzzentrum - Das virtuelle Fahrzeug), and A. Trifonova (Austrian Institute of Technology GmbH)

287

Carbon Disulfide As a Novel Additive for High-Performance Lithium Sulfur Batteries

S. Gu, J. Jin, Z. Wen, R. Qian, and S. Zhuo (Shanghai Institute of Ceramics, CAS)

288

Lithium Complex Hydride Solid-State Electrolytes with Conventional Liquid Electrolyte-like Conductivity

R. S. Kühnel (Empa), Y. Yan, A. Remhof, D. Rentsch (Empa - Swiss Federal Laboratories for Materials Science), Z. Lodziana (Institute of Nuclear Physics, Polish Academy of Sciences), and C. Battaglia (Empa - Swiss Federal Laboratories for Materials Science)

289

In Situ NMR Imaging: A Tool for Characterizing Ion Transport Properties in Li-Ion Battery Electrolyte Solutions

S. A. Krachkovskiy, D. Bazak (McMaster University), I. C. Halalay (General Motors Global Research & Development), B. Balcom (University of New Brunswick), and G. R. Goward (McMaster University)

290

Study of Crosslinked Solid Polymer Electrolyte for All-Solid-State Lithium Battery (Cancelled)

291

Garnet Based Electrolytes Based on Li_6.75La_3-XM_XZr_1.75Ta_0.25O_12-D for All Solid State Lithium Batteries: Systematic Doping on the Lanthanum Site with Two and Three-Valent Cations

M. Struzik, J. Genta, R. Pfenninger, I. Garbayo (Electrochemical Materials, ETH Zurich), and J. L. M. Rupp (Electrochemical Materials ETH Zurich)

292

Lithium Garnet Based All-Solid-State Batteries By Spark Plasma Sintering

J. Hodkinson (University of Cambridge)

293

Li-Garnet-Based Thin Film Processing for Novel Types of All Solid State Microbatteries

I. Garbayo, M. Pauker, M. Struzik, R. Pfenninger (Electrochemical Materials, ETH Zurich), and J. L. M. Rupp (Electrochemical Materials ETH Zurich)

294

Chemical Changes and Impedance Rise in Li₄Ti₅O₁₂- LiNi_0.5Co_0.2Mn_0.3O₂ Cells

R. Sahore, A. Tornheim, J. Bareno, Z. Zhang, and I. Bloom (Argonne National Laboratory)

295

Electrolyte Studies for High Voltage Lithium Ion Batteries

S. A. Delp, J. L. Allen, and T. R. Jow (U.S. Army Research Laboratory)

296

Interfacial Chemistry and Mechanics of Fluoroethylene Carbonate (FEC)-Derived Electrode/Electrolyte Interfaces

H. Shin (University of Michigan), J. Park (Missouri University of Science and Technology), and W. Lu (University of Michigan)

297

In Situ Engineering of the Electrode-Electrolyte Interface for Stabilized over-Lithiated Cathodes (Cancelled)

298

NMR Studies of Ion Transport in Ultra-Concentrated Aqueous Lithium Electrolytes

J. Peng (Hunter College of City University of New York), K. Xu (Center for Research on Extreme Batteries), C. Wang, L. Suo (University of Maryland, College Park), M. Gobet, S. Munoz, and S. Greenbaum (Hunter College, CUNY)

299

Optimization of Electrolytes for Si-Containing Full Cell

V. L. Chevrier (3M Corporate Research Materials Laboratory), R. Petibon (Dep. of Chemistry, Dalhousie University), C. Aiken (3M Electronic Materials Solutions Division), L. J. Krause, L. Jensen (3M Corporate Research Materials Laboratory), A. Xiao, D. B. Le, K. W. Eberman (3M Electronic Materials Solutions Division), and J. R. Dahn (Dalhousie University)

300

Cycling Intercalation Electrodes in Dinitriles Based Electrolytes for Li-Ion Batteries: Impact of Additives on the SEI Formation (Cancelled)

301

Phosphoranimine Electrolytes for Alkali-Ion Batteries

E. J. Dufek, J. R. Klaehn, J. S. McNally, and H. W. Rollins (Idaho National Laboratory)

302

Structural and Compositional Studies of Initial SEI Formation Employing Surface Sensitive Techniques

F. U. Renner (IMEC vzw. Division IMOMEC, Hasselt University), B. Moeremans (Hasselt University, Belgium), H. W. Cheng (Max-Planck-Institut f. Eisenforschung GmbH), and M. Valtiner (Max-Planck-Institut für Eisenforschung GmbH)

303

Electrolyte-Electrode Interactions and Interphases

S. M. Russell, A. V. Cresce (U.S. Army Research Laboratory), and K. Xu (Center for Research on Extreme Batteries)

304

Lattice Dynamics and Thermal Transport in Superionic Conducting Li₇La₃Zr₂O₁₂ Garnet

S. Wang (University of Washington), W. Qiu (Shanghai University), B. Duan (University of Washington), W. Zhang (Shanghai University), and J. Yang (University of Washington)

305

Stabilizing the Solid Electrolyte Interphase on Silicon-Based Anode Materials for Lithium-Ion Batteries By in-Situ Reductive Electropolymerization

B. Moeremans, Y. Zheng (Hasselt University), R. F. Duarte (Helmholtz-Zentrum Berlin), D. Deduytsche, C. Detavernier (Ghent University), M. Hahlin (Uppsala University), H. G. Boyen (Hasselt University), A. Hardy, M. K. Van Bael (imomec, imec), and F. U. Renner (IMEC vzw. Division IMOMEC)

306

Structure and Dynamics of the Lithium Ion Solvation Shell in Linear Organic Carbonates By Two-Dimensional Infrared Spectroscopy

K. D. Fulfer and D. G. Kuroda (Louisiana State University)

307

Investigation of the Interphase Between Graphite Electrode/ Ionic Liquid Electrolyte during the First Discharge (Cancelled)

308

Facile Chemistry Towards All Solid State Polymer Electrolytes and Lithium Ion Batteries (Cancelled)

309

Lithium Molten Salt Battery at Near Room Temperature Using Low-Melting Alkali Metal Melts

K. Kubota and H. Matsumoto (AIST)

310

Surface Film Formation on New Composite Anode: Impact of Electrolyte Additives

S. Sayah (Laboratoire PCM2E), F. Ghamouss (PCM2E E.A. 6299), J. Santos Pena (UNIVERSITE DE TOURS), D. Lemordant (PCM2E (EA6299) - Université François Rabelais de Tours), and F. Tran-Van (Université François Rabelais)

311

Rechargeable Lithium/PMMA-Libob-Tegdme/O₂ Battery (Cancelled)

312

Dopamine As an Electrolyte Additive for Lithium Secondary Batteries

H. Lee, T. Han, S. Kim, D. Jin (Hanbat National University), H. J. Kim (Sebang Global Battery Co., Ltd.), J. W. Rho (Sebang Global Battery CO., LTD), M. H. Ryou, and Y. M. Lee (Hanbat National University)

313

Effect of Electrolyte Amount on Electrochemical Properties of Coin-Type Lithium-Ion Cells

T. Han, H. Lee, S. Kim, M. H. Ryou, and Y. M. Lee (Hanbat National University)

314

Understanding Interfacial Resistance of Al-Substituted Li₇La₃Zr₂O₁₂ Solid Electrolyte

W. Chen (Illinois Institute of Technology, Lawrence Berkeley National Laboratory), L. Cheng, and M. Doeff (Lawrence Berkeley National Laboratory)

315

Graphite-Si Based Cell Performance in Alternative Electrolytes

T. L. Dzwiniel, K. Z. Pupek, G. Krumdick, and D. P. Abraham (Argonne National Laboratory)

316

Ionic Structure and Physical Properties of Fluorinated Alkyl-Phosphate Solutions Dissolving Lithium Salts

Y. Todorov, K. Fujii (Yamaguchi University), M. Aoki, H. Mimura (TOSOH F-TECH, Inc.), N. Yoshimoto, and M. Morita (Yamaguchi University)

317

Single-Solvent Electrolytes for Lithium-Ion Batteries Studied By Operando Diffusive Reflectance Infrared Fourier Transform Spectroscopy

J. Sicklinger, K. U. Schwenke, N. T. Zensen (TU München, TEC), and H. A. Gasteiger (Technische Universität München)

318

Development of Novel Electrolyte Additives for Designed Surface Modification

B. L. Lucht (University of Rhode Island)

319

The Performance of Lithium Bis(trifluoromethanesulfonyl)Amide in Propylene Carbonate on Binder Free Graphite Electrode

Y. Pan and B. L. Lucht (University of Rhode Island)

320

Synthesis and Characterization of Ba and Ta Substituted Garnet-Type Li₇La₃Zr₂O₁₂ Solid Electrolyte for All-Solid-State Lithium Battery

R. Inada, S. Yasuda, M. Tojo, R. Konishi, K. Tsuritani, Y. Yamashita, K. Okuno, T. Tojo, and Y. Sakurai (Toyohashi University of Technology)