315
Graphite-Si Based Cell Performance in Alternative Electrolytes

Monday, 20 June 2016
Riverside Center (Hyatt Regency)
T. L. Dzwiniel, K. Z. Pupek, G. Krumdick, and D. P. Abraham (Argonne National Laboratory)
In the quest to increase energy density of lithium-ion cells, graphite-silicon composite electrodes have been extensively investigated. The long-term performance of these electrodes is limited due to the instability of the electrode-electrolyte interface that is continually disrupted during the charge-discharge cycles. In order to improve the performance of silicon-based negative electrodes, researchers have developed various strategies that include novel electrolyte formulations among many others.

We conducted a comparative study of several electrolyte formulations based on LiFSI, LiTFSI, LiPF6, and mixtures thereof  in fluorinated carbonates like methyl 3,3,3-trifluoroethyl carbonate, bis(3,3,3-trifluoroethyl) carbonate, 3,3,3-trifluoropropylene carbonate, and monofluoropropylene carbonate.

Comprehensive data from rate study, impedance and cycle life evaluation in NCM523//Gr-Si CR2032 full cells will be presented and discussed.