The coin cells having 0.1 wt.% of dopamine exhibited an enhanced cycle performance at both high voltage (3.0~4.5V vs. Li/Li+, 25oC, C/2 rate) and elevated temperature (3.0~4.3V vs. Li/Li+, 55oC, C/2 rate). The improvement in the cycling performance is attributed to the suppression of transition metal dissolution in the cathode as well as the decomposition of both solvent and salt in the electrolyte due to the formation of the polydopamine on the surface of the cathode during the galvanostatic charge and discharge.
Acknowledgements
This work was supported by the Human Resource Training Program for Regional Innovation and Creativity through the Ministry of Education and National Research Foundation of Korea (NRF-2014H1C1A1066977) and by the Sebang Global Battery.
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