Recently, our group has developed techniques to fabricate ultrathin crystalline silicon nanotube arrays (Si NTAs). In comparison to previous works which focus on sealed SiNTs3 and larger size SiNTs (> 400 nm)4, our Si NTAs are ultrathin (10 nm) with porous side walls5. Fig.1 a & b, shows the SEM and TEM images of the Si NTAs fabricated by three step template directed method. The first step is the formation of sacrificial ZnO into stainless steel substrates followed by the deposition of Si onto the ZnO nanowires. The last step is the removal of the sacrificial ZnO nanowire templates to obtain the Si NTAs with porous side wall structure.
Fig. 1 (a) SEM and (b) TEM image of Si NTAs.
Fig. 2 shows the gravimetric capacity of Si NTAs as a function of cycle number. The electrochemical tests were performed in two electrode Swagelok cell. The half-cells were assembled by using Si NTAs as a working electrode, Li foil as a counter electrode, and a Whatman glass microfiber soaked in 1 M LiPF6 in EC:DEC electrolyte as separator. The cell was cycled at C/20 in a potential window of 0.01 – 1.75 V vs Li/Li+. It delivers a specific capacity of 1670 mAh.g-1 after 30 cycles. The high capacity values are attributed to the 3D porous structure of the Si NTAs.
During this work, the improved electrochemical performance of Si NTAs will be discussed.
Fig. 2. Gravimetric capacity vs cycle number for Si NTAs at C/20.
Reference
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3. Song, T.; Xia, J.; Lee, J.-H.; Lee, D. H.; Kwon, M.-S.; Choi, J.-M.; Wu, J.; Doo, S. K.; Chang, H.; Park, W. I., Arrays of sealed silicon nanotubes as anodes for lithium ion batteries. Nano letters 2010, 10 (5), 1710-1716.
4. Wu, H.; Chan, G.; Choi, J. W.; Yao, Y.; McDowell, M. T.; Lee, S. W.; Jackson, A.; Yang, Y.; Hu, L.; Cui, Y., Stable cycling of double-walled silicon nanotube battery anodes through solid-electrolyte interphase control. Nature nanotechnology 2012, 7 (5), 310-315.
5. Huang, X.; Gonzalez-Rodriguez, R.; Rich, R.; Gryczynski, Z.; Coffer, J. L., Fabrication and size dependent properties of porous silicon nanotube arrays. Chemical Communications 2013, 49 (51), 5760-5762.