Wednesday, 31 May 2017: 08:00
Grand Salon C - Section 18 (Hilton New Orleans Riverside)
Ionic liquids are attractive materials for alternative electrolytes to combat the safety issues associated with conventional organic carbonate-based electrolytes. However, the performance of ionic liquid-based cells is generally not competitive as the high viscosity and low conductivity limits the rate performance. The work presented here demonstrates that the drawbacks in terms of rate capability can be overcome through the use of the high lithium concentration Pyr12O1FTFSI0.6LiFTFSI0.4 electrolyte. Despite an order of magnitude difference in the conductivity and viscosity, this high concentration electrolyte outperforms the lithium-dilute electrolyte with the same components in terms of rate capability in LTO and LFP half and full cells. The results suggest that the effective Li ion transport in the concentrated electrolyte is higher than in the dilute solution.