In this study, a novel three-system composite MoS₂/rGO/Si-nanopowders was developed as an anode material for Li-ion batteries. The addition of Si nanopowders, which is reported as the anode material with the highest specific capacity for energy storage, further improved the widely investigated composite MoS₂/rGO anode for Li-ion batteries. MoS_2­/rGO composite was first synthesized through a hydrothermal method. Then, Si nanopowders were added to the matrix between MoS₂/rGO through a milling method. Composites having different ratios of Si nanopowders, MoS₂, and rGO were investigated in order to optimize the perfomance of the anode material. The electrical properties of the synthesized battery samples were evaluated using cyclic voltametry and charging-discharging test.