Designing New Magnesium-Based Cathode Materials

Tuesday, 3 October 2017: 11:20
Maryland A (Gaylord National Resort and Convention Center)
J. T. Vaughey, B. Key, D. L. Proffit, N. Sa, B. J. Ingram (JCESR at Argonne National Laboratory), A. L. Lipson (Argonne National Laboratory), K. Poeppelmeier, and J. T. Incorvati (Northwestern University)
Lithium-ion batteries have been a mainstay of the consumer electronics industries for nearly 25 years. Unlike many older energy storage systems, lithium-ion does not describe a specific chemistry but a family of chemistries and a mechanism of operation. As a result numerous types of materials are under the umbrella of lithium-ion batteries that can be modified and developed to meet a variety of end-user goals. Looking beyond-lithium ion, the landscape is less understood and explored. One of our research efforts is to look at non-lithium cation based energy storage chemistries, including the MgxV2O5 and MgxV2O5*H2O systems. This talk will focus on recent developments from our lab in Mg-ion and Ca-ion chemistries with highlighting new types of cathodes, electrolytes, and anode materials1-5


(1) Lipson, A.L; Han, S.-D; Kim, S. Pan, BF; Sa, N.; Liao; C, Fister, TT; Burrell, AK; Vaughey, JT; Ingram, BJ J. Power Sources 325 646-652 (2016).

(2) Sa, N; Wang, H; Proffit, DL; Lipson, AL; Key, B; Liu, M; Feng, ZX; Fister, TT; Ren, Y; Sun, CJ; Vaughey, JT; Fenter, PA; Persson, KA; Burrell, AK J. Power Sources 323 44-50 (2016).

(3) Sa, N; Kinnibrugh, TL; Wang, H; Gautam, GS; Chapman, KW; Vaughey, JT; Key, B; Fister, TT; Freeland, JW; Proffit, DL; Chupas, PJ; Ceder, G; Bareno, JG; Bloom, ID; Burrell, AK Chemistry of Materials, 28(9) 2962-2969 (2016).

(4) Lipson, AL; Han, SD; Pan, B; See, KA; Gewirth, AA; Liao; Vaughey, J; Ingram, BJ J. Electrochem. Soc., 163(10) A2253-A2257 (2016).

(5) Mukherjee, A.; Sa, N.; Phillips, P.; Burrell, AK; Vaughey, JT; Klie, R. Chemistry of Materials, 29, 2218−2226 (2017).