An example of the performance of a thick-film high temperature thermistor sensor produced in this work is shown in Figure 1. The sensor material in the embedded thermistor consisted of a patterned electrically conducting oxide buried within a laminate yttrium-stabilized zirconia (YSZ) substrate. The oxide sensor composition was initially printed on green YSZ substrates, laminated into a preform, and then sintered to 1400°C. The sintered preforms were embedded into chromia-based refractory bricks. The cast bricks were then sintered to 1450°C for 10 hrs in air. After sintering, the bricks were trimmed to expose the sensor material. Platinum wire, platinum mesh, and additional sensor ink was used to make connection to the sensor embedded inside a brick. Prior to testing, the assembled leads were heat treated to 1400°C to pre-sinter the sensor to wire connection. To collect data for Figure 1, the sensor to wire connection was placed at the same level as high temperature refractory for the furnace door with additional insulation to mimic typical high temperature furnace refractory configuration. With this testing arrangement, the leads connection was exposed to only about 500°C maximum temperature over the course of the test. With the leads outside the hot zone, the resistance drift during the temperature hold was recorded from 9.7 to 9.1 ohms over 20 hours.
Acknowledgements:
The authors would like to acknowledge the financial support of DOE NETL under contracts DE-FE0012383 and DE-FE0026171. The authors would also like to acknowledge West Virginia University Shared Research Facilities for support through materials characterization.
Figure 1. Resistance and temperature profile of conductive oxide based thermistor co-sintered inside ceramic substrate and imbedded in a chromia-based brick. The brick was tested to 1350°C.