A series of DBC and DBA substrates, composed of Al and Cu as metal layers and of Al2O3, AlN and Si3N4, were examined by thermal shock test between -50 °C and 250 °C. DBC substrates with Al2O3 and AlN fractured only after 10 cycles due to severe thermal stress while all DBA and DBC with Si3N4 substrates survived. Al and Cu layer of all DBC and DBA substrates severely deformed by thermal shock. By microstructural observation, grain boundary sliding during thermal shock has a key to cause deformation of metal layers on ceramics. Ni and Ni-P plating on metal layer also deformed followed by Al and Cu layer deformation. Ni-P plating showed severe cracking which can be attributed to brittleness of Ni-P plating while Ni plating did not.
Ag sinter joining can be successfully applied for die attach by low temperature and low pressure bonding in air. For better bonding quality, Ag coating is the best metallization due to the specific reaction of Ag in air. By modifying solvent, Ag particles paste was modified to form a good bonding with Au surface finish. It can provide not only high temperature structural stability but also excellent thermal dissipation capability. High die-shear strength beyond 30 MPa was maintained by thermal shock between -50 °C and 250 °C up to 1000 cycles for a DBC die-attach structure. The thermal resistance of Ag sinter joined die attach is much lower than that of solder. Figure shows the example of a GaN die-attached on DBC substrate with a new Ag sinter materials at 200 °C in air without any pressure. Even on the Au metallization, the GaN die was bonded with high strength. The interface shows a good bonding between Au and Ag.
This work was supported both by JST ALCA project on GaN packaging and by METI standardization project for evaluation methods of thermal properties of ceramics substrates.