This study investigates the effect of various blinding agents on the main components of a gold-containing concentrate: carbon, gold and pyrite. A novel electrochemical approach is employed, i.e. double-layer capacitance measurements combined with electro-oxidation/reduction peaks obtained from cyclic voltammetry tests. Our group is the first to employ the electric double-layer theory to study the preg-robbing capacity of carbonaceous ores with total carbonaceous matter (TCM) contents as low as 0.3 % by weight.
Figure 1 shows a comparison between the blinding activity, and durability, of various surfactants and chemical reagents, at different concentrations, on the surface of activated carbon particles over a 24-hour contact period. The capacitance is an indication of how well the chemical reagents have been adsorbed on the activated carbon particles with the lowest capacitance values showing the best surface adsorption. The study reveals that kerosene, Lecithin and Polymax 30 are among the best blinding agents for the activated carbon surfaces in terms of adsorption and durability.
Further cyclic voltammetry studies on gold surfaces in alkaline cyanide solutions (with the added blinding agents) have shown that kerosene is the least detrimental to the gold cyanide leaching process, i.e. the electrochemical oxidation reaction for the formation of AuCN complex.
Figure 1. A comparative study for the effect of various chemical reagents, i.e. Aristonate H and L, Lecithin, Sodium dodecyl sulfate (SDS), kerosene and Polymax 30, on the ion adsorption capability of the activated carbon particles over 24 hours.
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