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Influence of Electrode Distance on the Electrochemical Reduction of CO2 in Aqueous Solution

Tuesday, 2 October 2018
Universal Ballroom (Expo Center)
J. Liu, Y. Zhou, L. Peng, J. Qiao (Donghua University), and J. Jung (Wattech Power Inc.)
At present, the research on the electrochemical reduction of CO2 (ECR-CO2) mainly focuses on the electrode material and the catalyst. However few studies involved the reactor and reaction conditions. In this study, the commerical available nano-Sn catalyst was coated on a gas diffusion electrode to form a working electrode (Sn/GDE), the influeces of distance between the aonde and the cathode were systematically investigated in a reactor for ECR-CO2. The experiments show that for the electrode distance chnaged from 1.5 cm to 5.7 cm, both current density and Faradaic efficiency were decreased sharply from 34.6 to 10.4 mA cm-2 and 80% to 60%, respectively. However, the distance of 3.3 cm seems to be a critical point, at which the current density was no longer changed.