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Correlations between Electrochemical Performance of Aluminum Battery and Graphite Characteristics of Carbon Cathode

Wednesday, 3 October 2018
Universal Ballroom (Expo Center)
S. C. Chiu, Y. L. Li, P. I. Pan, C. C. Chiang, and C. C. Yang (Industrial Technology Research Institute)
Rechargeable aluminum battery is promising to replace lead-acid battery for energy storage systems (ESSs) and vehicle cranking system because of non-flammability, ultra-fast charge and discharge capability, environmental-friendliness, and long cycle life. However, Al battery is hindered by low working voltage, low specific capacity of cathode materials, high cost of ionic liquids (ILs) and high self-discharge rate. The first two obstacles are highly related to cathode materials. In this study, electrochemical properties (e.g., cyclic voltammetry and galvanostatic charge/discharge) of Al battery using natural graphite, artificial graphite, soft carbon and hard carbon as cathode materials are investigated. At a current 100 mA/g, natural graphite (loading density of 13 ± 2 mg/cm2) shows the highest discharge capacity of 98 mAh/g. Raman spectroscopy and X-ray diffraction (XRD) are also employed to explore carbon properties, causing different energy storage performance. We suggest carbon, natural graphite, with low-disorder graphite structure delivers high capacity.