One way to reduce the PS shuttling is to employ electrolytes that only sparsely dissolve sulfur and PS.3, 4 Here we have employed several such electrolytes based on fluorinated carbonates and ethers and studied the resulting performance including the cycle life of the Li-S battery cells made. By combining physico-chemical characterization, electrochemical performance assessments, and operando confocal Raman spectroscopy we gain a better understanding of the PS formation. The overall outcome can be used to guide the selection of solvents for more performant Li-S batteries.
The research presented has received funding through the HELIS project (European Union’s Horizon 2020 research and innovation program under Grant Agreement No. 666221).
References
1 Q. Pang, X. Liang, C. Y. Kwok and L. F. Nazar, Nat. Energy, 2016, 1, 1–11.
2 P. Bonnick, E. Nagai and J. Muldoon, J. Electrochem. Soc., 2018, 165, A6005–A6007.
3 S. Drvarič Talian, S. Jeschke, A. Vizintin, K. Pirnat, I. Arčon, G. Aquilanti, P. Johansson and R. Dominko, Chem. Mater., 2017, 29, 10037–10044.
4 S. Gu, R. Qian, J. Jin, Q. Wang, J. Guo, S. Zhang, S. Zhuo and Z. Wen, Phys. Chem. Chem. Phys., 2016, 18, 29293–29299.