Except of doping, one of the major issues to extend the functional range of nanotubes is to coat homogenously tube interiors by a secondary material. It has been shown that additional ultrathin surface coating of TiO2 by secondary materials such as Al2O3 [4], ZnO [5] or MgO [6] annihilates electron traps at the TiO2 surface and thus increases the photogenerated concentration of charge carriers. Recently, it has been demonstrated that just a single cycle of Al2O3 [7] or ZnO [5] deposited by atomic layer deposition (ALD) efficiently improve charge transport properties of the heterostructure while gradual passivation appears with increasing ZnO thickness due to stronger band-bending [5].
The presentation will focus in detail on the coating of the nanotube arrays by secondary materials using ALD. The deposited materials influence strongly photo-electrochemical properties of nanotube films. Experimental details and some very recent photocatalytic [8] and sensing [9] results will be presented and discussed.
References:
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[4] R. Zazpe et al., Langmuir, in press, DOI: 10.1021/acs.langmuir.6b03119.
[5] A. Ghobadi et al., Scientific Reports 6 (2016) 30587
[6] H. Park, et al., Journal of Electroceramics 23 (2009) 146.
[7] J-Y. Kim et al., Nanotechnology 25 (2014) 504003.
[8] M. Krbal et al., Ms submitted.
[9] S. Ng et al., Ms in preparation.