Synergistic Effects from Substrate and Electrolytes on Li Deposition

Thursday, 5 October 2017: 16:10
National Harbor 8 (Gaylord National Resort and Convention Center)
J. A. Lochala, B. Wu (University of Arkansas), T. Tarverne (SUNY Polytechnic Institute), and J. Xiao (Pacific Northwest National Laboratory)
Li metal has been considered the “holy grail” anode materials. Li metal has the most negative potential with an extremely high theoretical specific capacity of 3860 mA h g−1.[1] It is, however, plagued with multiple challenges which need solutions before the realization of this material. Li metal has two main failure mechanisms, one is the random growth of detrimental dendrites, which can lead to rapid thermal runoff, i.e. Galaxy Note 7.[2] The other issue that arises upon cycling is pulverization of lithium metal through none uniform plating, leading to an increase in solid electrolyte formation(SEI) and thereby the increase in voltage polarization within the cell.[3] Both Li failure mechanisms are rooted in the uneven distribution of SEI layers whose properties vary depending on the location of SEI formed.[4] The initial surface chemistry on Li metal influences SEI formation in the very beginning. In this work, electrochemical deposition of Li metal on specific substrate has been performed to understand the nucleation and growth of Li crystals. Electrolyte and substrate have been identified to have synergistic effects on the morphology and efficiency of deposited Li. The fundamental mechanisms that dictates the smooth Li deposition will be discussed.


1) Xu, W., Wang, J., Ding, F., Chen, X., Nasybulin, E., Zhang, Y. and Zhang, J.G., 2014. Lithium metal anodes for rechargeable batteries. Energy & Environmental Science7(2), pp.513-537.

2) Cohen, Y.S., Cohen, Y. and Aurbach, D., 2000. Micromorphological studies of lithium electrodes in alkyl carbonate solutions using in situ atomic force microscopy. The Journal of Physical Chemistry B104(51), pp.12282-12291.

3) Lu, D., Shao, Y., Lozano, T., Bennett, W.D., Graff, G.L., Polzin, B., Zhang, J., Engelhard, M.H., Saenz, N.T., Henderson, W.A. and Bhattacharya, P., 2015. Failure mechanism for fast‐charged lithium metal batteries with liquid electrolytes. Advanced Energy Materials5(3).

4) Aurbach, D., Zinigrad, E., Cohen, Y. and Teller, H., 2002. A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions. Solid state ionics148(3), pp.405-416.