(Invited) SURMOFs and CCNCs As Novel Tuneable Materials for Electronic Devices and Applications

Wednesday, 4 October 2017: 10:50
Chesapeake E (Gaylord National Resort and Convention Center)
E. Redel (Karlsruhe Institute of Technology)
Here we present a particularly interesting class of surface-anchored (metal-organic frameworks andcoordination network compounds) materials SURMOFs and (conductive coordination network compounds) CCNCs for the fabrication e.g. of 1D (Photonic Band Gap) PBG materials [1,2] as optical sensors, low-k dielectric thin films [3],optoelectronic/electrochromic switchable coatings/devices [4] microelectronic devices, e.g. RRAM devices [5] or Hybrid-Materials NPs@SURMOFs for future artificial Light-Harnessing (LH) assemblies and photocatalysts.[6]

Since these materials are highly porous and the size of their pores are highly adjustable, they can be further functionalized and further tailor to electrically load and unload small ions (optoelectronic applications) or act as photon traps, which are able to efficiently absorb, transport and harness light energy over an artificial LH antenna array.[7] An outlook will be given for highly conductive and porous CCNCs thin film materials as well as further electronic characterization of SURMOFs and CCNCs.


[1] J. Liu, E. Redel, S. Walheim, Z. Wang, V. Oberst, J. Liu, S. Heissler, A. Welle, M. Moosmann, T. Scherer, M. Bruns, H. Gliemann, C. Woell Chemistry of Materials (ACS) 2015, 27, 1991-1996.

[2] J. P. Best, J. Michler, J. Liu, Z. Wang, M. Tsotsalas, X. Maeder, S. Roese, V. Oberst, J. Liu, S. Walheim, H. Gliemann, P. G. Weidler, E. Redel and C. Woell Appl. Phys. Lett. 2015, 107, 101902.

[3] E. Redel, Z. Wang, S. Walheim, J. Liu, H. Gliemann, C. Woell, App. Physics Lett. 2013, 103, 091903 [4] J. Liu, W. Zhou, S. Walheim, Z. Wang, P. Lindemann, S. Heissler, J. Liu, P. G. Weidler, T. Schimmel, C. Woell, E. Redel Optics Express (OSA) 2015, 23, 13725-13733.

[5] Z. Wang, D. Nminibapiel, P. Shrestha, J. Liu, K. P. Cheung, W. Guo, P. G. Weidler, H. Baumgart, C. Woell, E. Redel (Back Cover Issue 1/02 2016) ChemNanoMat (Wiley-VCH) 2016, 2, 67-73.

[6] W. Guo, C. Zhi, C. Yang, T. Neumann, C. Kuebel, W. Wenzel, A. Welle, W. Pfleging, O. Shekhah, C. Woell, E. Redel Nanoscale (RSC) 2016, 8, 6468-6472.

[7] J. Liu, W. Zhou, J. Liu, I. Howard, G. Kilibarda, S. Schlabach, D. Couprey, M. Addicoat, S. Yoneda, Y. Tsutsui, T. Sakurai, S. Seki, Z. Wang, P. Lindemann, E. Redel, T. Heine, C. Woell *VIP ≡ Very Important Paper (Angewandte Front Cover Issue 2015-54/25) Angewandte Chemie International Edition (Wiley-VCH) 2015, 54, 7441-7445.